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大学生化学通讯科训成果

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Peroxidation damage and antioxidative capability of Ceratophyllum demersum under NH4+-N stre

氨态氮胁迫下金鱼藻的过氧化损伤和抗氧化能力

高镜清、马娜、周俊、王文垅、熊治廷、陈娜

Journal of Freshwater Ecology, 2012, 27(4):539-549.

The current article investigated the effects of ammonia nitrogen concentration and pH on peroxidation damage and antioxidative capability of Ceratophyllum demersum.The pH ranges (7 and 9) were carefully controlled to distinguish between the effects of unionized ammonia(NH3) and ionized ammonia (NH4+).The addition of ammonia significantly decreased chlorophyll a content.Peroxidase and superoxide dismutase activities as well as glutathione content under high ammonia conditions (10 mg N/L) significantly increased at pH 7 but were no different or reduced at pH 9.Catalase activity as well as ascorbic acid and malondialdehyde contents significantly increased under all ammonia treatments at pH 7 and 9.C.demersum suffered from stre at pH 9 under high ammonia conditions.Higher pH in water may induce C.demersum to exhibit more severe physiological responses.*马娜,2011级本科生,学号20112310317,在本论文中为第二作者。 *国家自然科学基金资助项目(No.J1210060)

Synthesis and Structures of Silver(I) and Copper(I) 3,5-Dipentyl- 1,2,4- Triazolates

银(I)和铜(I)与3,5-二戊基-1,2,4-三氮唑生成的配合物的合成及结构 张文华、王永辉、李亚威、杨光

J.Clust.Sci.2012, 23:411–420.

The Ag(I) and Cu(I) complexes of 4-amino-3,5-dipentyl-4H-1,2,4-triazole (4-NH2-3,5-(C5H11)2tz) and 3,5-dipentyl-1H-1,2,4-triazole (3,5-(C5H11)2tzH) have been synthesized and characterized.X-Ray analysis shows that {Ag4[4-NH2- 3,5-(C5H11)2tz]6}(BF4)4 is a tetranuclear complex featuring an Ag4tz6 cluster; {Ag[3,5-(C5H11)2tz]}n exhibits a 3D structure of lvt-a topology; and {Cu2[3,5- (C5H11)2tz]Br}n is a Cu4Br4-cluster based 3D complex with the dia topology.

*李亚威,2010级本硕班本科生,学号20102310614,在本论文中为第三作者。

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